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Analysis of the state of cathode active materials using XPS.

For the evaluation of lithium-ion battery materials! Analyzing chemical bonding states using X-ray photoelectron spectroscopy.

Regarding the NMC reagent, an evaluation of the valence of metal oxides was conducted through state analysis using XPS. Qualitative analysis was performed on commercially available NMC reagents, yielding values for the NiMnCo ratio that are close to the specifications of the reagent. Additionally, F and C, which are believed to originate from the binder components, were also detected. 【Analysis of NMC Reagent (Partial)】 ■ The main oxides of Ni, Mn, and Co are inferred to be NiO (Ni2+), MnO2 (Mn4+), and Co3O4 (a mixed valence of Co2+ and Co3+). ■ C, O, and F show peak shifts consistent with organic compounds believed to originate from the binder. ■ Peak assignments were inferred based on various literature and databases. *For more details, please download the PDF or feel free to contact us.

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State analysis using EPMA

Estimate bonding states by comparing with standard spectra! Introducing state analysis using EPMA.

In the state analysis using EPMA, changes (shifts and shapes) in the characteristic X-ray peak wavelengths due to differences in the chemical bonding states (ionic valence, crystal structure, coordination number) of oxides and silicates are utilized to estimate the bonding states by comparing with standard spectra. In the identification of two types of copper oxides, when distinguishing between black CuO and red Cu2O by color is difficult, especially for microscopic objects that require an electron microscope, it is possible to grasp the oxidation state using EPMA. Additionally, while XPS is effective for measuring thin oxide layers on aluminum surfaces, EPMA can be used to understand the oxidation state of small foreign particles, bulk materials, and composites. 【Device Specifications】 ■ Manufacturer: JEOL Ltd. Jeol-8200 ■ Analysis Method: Wavelength Dispersive X-ray Analysis (WDX) ■ Analyzable Elements: B to U ■ Energy Resolution: 20 eV (EDX is approximately 130 eV) ■ Detection Limit: 0.01% and above ■ Maximum Sample Size: 100x100 mm *For more details, please refer to the PDF document or feel free to contact us.

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